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Castiel suggests that a guilty-feeling Dean take some time off as things are quiet, however, in Tulsa, Oklahoma, a mysterious red-haired woman (Ruth Connell) sits in a hotel room under two men staked to the ceiling.Following Dean becoming human again, he and Sam have taken a break from hunting, until they find what seems to be a werewolf case in Durham, Washington.
At a gas station, they are attacked by a vengeful Adina and a weakened Castiel is left near-death.As the ritual goes on, Dean taunts Sam over his desperate attempts to find him, including tricking a man into selling his soul so he could interrogate a crossroads demon.Unknown to Sam, the ritual makes Dean human enough that he is able to escape and he stalks Sam throughout the bunker. They are able to successfully complete the ritual and Dean is returned to being human, but retains the Mark of Cain.Realizing that the situation has gotten out of his control, Crowley contacts Sam with Dean's whereabouts to have Sam handle his brother.Sam offers to help Dean become human again, but Dean is uninterested, having found a kind of liberty in being a demon and in not caring anymore.Dean gets a call from the man, who demands that Dean trade himself for Sam's life.
However, Dean doesn't care about his brother anymore, refuses the deal, and hangs up, leaving Sam in the kidnapper's hands.Sam seizes the opportunity to capture the distracted Dean.In return for Crowley's help, Sam gives him the First Blade.Elsewhere, a dying Castiel (Misha Collins) is approached by Hannah (Erica Carroll), one of his followers in the previous season, for help tracking down Daniel and Adina (Jud Tylor), two rogue angels who refuse to return to the restored Heaven, instead wanting the freedom that life on Earth gives them.While Castiel is understanding towards the couple, Hannah is not, and a fight ensues that results in Castiel having to kill Daniel to save Hannah.Cole, having learned about Dean's demonic nature, starts researching the supernatural, still determined to take revenge on Dean.